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Generally, activated abilities can be activated any time you have priority, like an Instant or a spell with Flash

While I don't expect that outcome from Nature's Rhythm, I do think the card can see play in Standard and Commander for sure, and possibly in very specific decks that can take advantage of the harmonize flashback mode in other formats

Unlike standard booster pulls, each copy symbolizes competitive mastery, bearing a unique serial number that heightens its collectible prestige

If you have to choose between the two, go with Kangaskhan if you want to deliver damage (60 DMG if you get 2 heads, 30 DMG on 1 head, and 0 DMG if both tails) along with 20 DMG from Rocky Helmet